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style="line-height:2.5;font-size:16px;">**氧化技術(AdvancedOxidationProcesses簡稱AOPs)是近20年來水處理領域興起的新技術，通常指在環境溫度和壓力下通過產生具有高反應活性的羥基自由基</span><span style="line-height:2.5;font-size:16px;">來氧化降解有機污染物的處理方法。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">其中是否產生并利用羥基自由基進行氧化是區別于傳統氧化與**氧化技術的根本所在。而如何通過合適的手段產生更多的羥基自由基則是判定某項**氧化技術是否具有發展前景的關鍵。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">傳統化學氧化：<a href="http://www.mtvcircle.com/" target="_blank"><strong>臭氧氧化</strong></a>、雙氧水氧化、高錳酸鉀氧化及二氧化氯氧化等。**氧化技術主要包括:濕式氧化(WAO)、光化學催化氧化、臭氧催化氧化以及芬頓氧化等。</span> </p> <p style="text-align:center;"> <span style="line-height:2.5;"><img src="http://img.dlwjdh.com/upload/10469/200901/5e1b4957261999f8b0b0c85e10939027.jpg" alt="" /><br /> </span> </p> <p style="text-align:left;text-indent:2em;"> <span style="line-height:2.5;"></span> </p> <p style="text-indent:2em;"> <strong><span style="color:#003399;font-size:18px;line-height:2.5;">非均相臭氧催化氧化</span></strong> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;"><strong><a href="http://www.mtvcircle.com/" target="_blank">西安臭氧催化劑</a></strong>氧化技術為-種采用一系列臭氧多相催化氧化的方法去除廢水中的污染物或改變污染物狀態的**氧化技術。該技術通過引發具有強氧化能力的羥基自由基，強化分解水中高穩定性、難降解有機污染物，對高穩定性有機污染物的分解效率比單純<strong><a href="http://www.mtvcircle.com/" target="_blank">臭氧氧化</a></strong>提高數倍甚至數十倍，顯著提高了出水的安全性及污水的可生化性。同時，催化劑還可提高水中臭氧的分解能力，增加水中溶解氧的濃度，并強化后續生化處理工藝的去除效率。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">非均相催化劑(固態)與反應溶液處于不同相，反應在固-液相進行的氧化方法稱為多相催化臭氧氧化法。近年來，多相催化臭氧氧化技術已經成為去除水中高穩定性、難降解有機污染物的關鍵技術之一。利用非均相固態催化劑協調臭氧氧化可以降低反應活化能或改變反應歷程，從而達到深度氧化并提高廢水可生化性的目的。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">氧化還原反應的特征是在反應中有電子從一個物質(還原劑)轉移到另一個物質(氧化劑)，任何化學物質的氧化還原特性都可以用標準氧化還原電位來確定。臭氧具有較高的標準氧化還原電位，在所有的原子中僅比氟原子、氧原子、OH.自由基低，所以臭氧分子可以和大多數有機物發生氧化還原反應。這種反應能力在與某些無機物(如Fe2+等) 的反應過程中也是非常重要的。但是，對于大多數的臭氧反應一般不發生直接的電子轉移到其它物質。</span> </p> <p style="text-align:center;"> <img src="http://img.dlwjdh.com/upload/10469/200901/b3f916c4cdab1eefbb6c10bbe57d8162.jpg" alt="" /> </p> <p style="text-align:left;text-indent:2em;"> <span style="line-height:2.5;font-size:18px;color:#003399;"><strong>采用非均相<a href="http://www.mtvcircle.com/" target="_blank">臭氧催化氧化</a>的必要性</strong></span> </p> <p style="text-align:left;text-indent:2em;"> <span style="line-height:2.5;background-color:#FFFFFF;color:#003399;font-size:18px;"><strong>A：氧化方法對比</strong></span> </p> <p style="text-align:center;"> <img src="http://img.dlwjdh.com/upload/10469/201013/886461211e73dcc4d79b0f9c7068a9e1.png" alt="" width="400" height="300" title="" align="" /> </p> <p style="text-align:left;text-indent:2em;"> <span style="line-height:2.5;background-color:#FFFFFF;color:#003399;font-size:18px;"><strong>B：臭氧直接氧化有機物過程</strong></span> </p> <p style="text-align:center;"> <img src="http://img.dlwjdh.com/upload/10469/200901/3aba9b075e9b30784ebe64f0ab4ac2ab.jpg" alt="" /> </p> <p style="text-align:left;text-indent:2em;"> <br /> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">臭氧具有親電性，對含雙鍵的有機物、胺、苯環、含硫有機物等氧化速率快，但其氧化反應階段大多停留于加氧或初步開環階段，顯然氧化能力及深度均不夠。而針對其它的有機物氧化速率則相對較慢，甚至低于臭氧自身分解速度，具有較強的選擇性。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:18px;color:#003399;"><strong>C：廢水中殘留的難降解類有機物分類</strong></span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">1)含氮雜環類:基本上不為生物所氧化，通過生化處理其降解率不到1%，這類型有機物難生化、難氧化有機物是構成污水中殘留有機物的主要成分之一。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">2)可溶性微生物產物SMP(SolubleMicrobialProducts):二段生化出水中還包括生化處理過程中所自產的可溶性微生物產物(SMP)，有機成**括微量沒有消耗完的可利用底物和生化過程中產生的SMP。SMP是可以生物降解的,但是其降解速度極慢。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">因此，對臭氧進行催化氧化使其產生氧化能力更強且幾乎無選擇性的羥基自由基是十分有必要的。</span> </p> <div style="text-align:center;"> <span style="text-indent:2em;"><img src="http://img.dlwjdh.com/upload/10469/200901/2660a2bb40d42a150e632536e6796b90.jpg" alt="" /></span> </div> <p style="text-indent:2em;"> <span style="line-height:2.5;color:#003399;font-size:18px;"><strong>非均相臭氧催化氧化工藝系統構成</strong></span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;background-color:#FFFFFF;color:#003399;font-size:18px;"><strong>A：臭氧溶解及分布系統</strong></span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">利用某種方式使得臭氧化氣體與待處理廢水進行混合、溶解及分配的過程裝置，大體有穿孔氣水混合方式、微孔布氣氣水混合方式、壓力射流氣水混合及分布方式等。我司設計團隊可依據不同水質及要求匠心打造，在我司專屬催化劑的協助下，可將臭氧的利用率提高至90%以上。臭氧溶解效果及利用率是影響其催化氧化效果的關鍵因素之一。</span> </p> <p style="text-align:center;"> <span style="line-height:2.5;"><img src="http://img.dlwjdh.com/upload/10469/200901/1d2dcf7e55cffc4db1eb7a7499c81377.jpg" alt="" /><br /> </span> </p> <p style="text-align:left;text-indent:2em;"> <span style="line-height:2.5;"><strong><span style="background-color:#FFFFFF;color:#003399;line-height:2.5;font-size:18px;">B：催化塔體或池體</span></strong><br /> </span> </p> <p style="text-align:left;text-indent:2em;"> <span style="line-height:2.5;"> </span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">催化反應工藝主體平臺，具備**的進、出水裝置、承托及氣水二次或多次分配裝置、反洗裝置等。此外，為提高反應效率，塔或池的外形結構、材質及內構件配備需采取專業特殊設計。</span> </p> <p style="text-align:center;"> <img src="http://img.dlwjdh.com/upload/10469/200901/1c972605020e6006a48834a44ab38871.jpg" alt="" /> </p> <p style="text-align:left;text-indent:2em;"> <br /> </p> <p style="text-indent:2em;"> <strong><span style="background-color:#FFFFFF;color:#003399;line-height:2.5;font-size:18px;">C：**催化劑</span></strong> </p> <p style="text-indent:2em;"> <span style="text-indent:2em;line-height:2.5;font-size:16px;">催化劑是催化臭氧轉化產生羥基自由基的核心構件。聚光環保自主研發發明..產品JG-8CH型高性能臭氧催化劑具有較為廣譜的適應性。尤其在石化行業廢水處理、制藥行業廢水處理、煤化工行業廢水處理以及部分精細化工廢水處理上取得了十分理想的催化處理效果。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">JG-8CH型高性能臭氧催化劑精心選用Cu、Fe、Ni、Co、Mn等過渡金屬中的活性組份進行制備。采用均勻分配及競爭附著的手段將其進行**生產，以達到.佳的原位催化、表面吸附及分散均勻等特點。</span> </p> <p style="text-indent:2em;"> <span style="line-height:2.5;font-size:16px;">聚光環保緊緊圍繞如何提高催化劑的催化效能和臭氧的利用率做了大量的研究并經多年的工程檢驗，產品性能已非常成熟。然而，我司并未局限于現有成績，而是在技術上不斷精進。到目前為止，公司生產的臭氧催化劑已經發展到第三代產品，該催化劑(JG-8CH型催化劑)由于具備了多種催化活性組份共存，且分散均勻、孔徑適中等優點，可提高羥基自由基的產生量達300%~500%，大幅增強了臭氧的催化氧化能力。</span> </p> <p style="text-align:center;text-indent:2em;"> <span style="line-height:2.5;"></span><img src="http://img.dlwjdh.com/upload/weijin.jpg?/upload/10469/200901/322fd00e91a8e84e95b125c6fff0ab2d.jpg" alt="" /><img src="http://img.dlwjdh.com/upload/10469/200901/cc493a88f64485d987f537524ab8184a.jpg" alt="" /> </p> <p style="text-align:left;text-indent:2em;"> <strong><span style="background-color:#FFFFFF;color:#003399;line-height:2.5;font-size:18px;">D：臭氧催化氧化處理效果對比</span></strong> </p> <p style="text-align:center;text-indent:2em;"> <span style="line-height:2.5;"></span><img 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